ICSC 1767 - TEBUPIRIMFOS

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TEBUPIRIMFOS	ICSC: 1767 (April 2013)
Phostebupirim Tebupirimphos 5-(4-chlorophenyl)-5-(dimethoxymethyl)-3-methylimidazolidine-2,4-dione

CAS #: 96182-53-5

UN #: 3018

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	In case of fire in the surroundings: all extinguishing agents allowed.

PREVENT GENERATION OF MISTS! IN ALL CASES CONSULT A DOCTOR!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Pupillary constriction, muscle cramp, excessive salivation. Muscle twitching. Convulsions. Dizziness. Sweating. Nausea. Laboured breathing. Unconsciousness.	Use local exhaust.	Fresh air, rest. Refer immediately for medical attention.
Skin	MAY BE ABSORBED! See Inhalation.	Protective gloves. Protective clothing.	Wear protective gloves when administering first aid. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer immediately for medical attention.
Eyes		Wear face shield in combination with breathing protection.	Rinse with plenty of water (remove contact lenses if easily possible). Refer for medical attention.
Ingestion	See Inhalation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rest. Rinse mouth. Refer immediately for medical attention.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: complete protective clothing and face shield. Do NOT let this chemical enter the environment. Collect leaking liquid in covered containers. Store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Fatal if swallowed, in contact with skin or if inhaled May cause damage to the nervous system May cause damage to nervous system through prolonged or repeated exposure Very toxic to aquatic life Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: I
STORAGE
Separated from food and feedstuffs. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
PACKAGING
Do not transport with food and feedstuffs.

TEBUPIRIMFOS

ICSC: 1767

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance AMBER OR BROWN LIQUID. Physical dangers Chemical dangers On combustion, forms toxic and irritating fumes.	Formula: C₁₃H₂₃N₂O₃PS Molecular mass: 318.4 Boiling point: 152°C Solubility in water at 20°C: very poor Vapour pressure, Pa at 20°C: 0.04 (negligible) Density: 0.59-0.67 g/cm³ Octanol/water partition coefficient as log Pow: 4.2

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
AMBER OR BROWN LIQUID.

Physical dangers

Chemical dangers
On combustion, forms toxic and irritating fumes.

Formula: C₁₃H₂₃N₂O₃PS
Molecular mass: 318.4
Boiling point: 152°C
Solubility in water at 20°C: very poor
Vapour pressure, Pa at 20°C: 0.04 (negligible)
Density: 0.59-0.67 g/cm³
Octanol/water partition coefficient as log Pow: 4.2

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body in hazardous amounts by ingestion, through the skin and by inhalation. Effects of short-term exposure Cholinesterase inhibition. The substance may cause effects on nervous system.	Inhalation risk A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C. Effects of long-term or repeated exposure Cholinesterase inhibition. This may result in nervous system impairment.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body in hazardous amounts by ingestion, through the skin and by inhalation.

Effects of short-term exposure
Cholinesterase inhibition. The substance may cause effects on nervous system.

Inhalation risk
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
Cholinesterase inhibition. This may result in nervous system impairment.

OCCUPATIONAL EXPOSURE LIMITS
TLV BEI issued

ENVIRONMENT
The substance is very toxic to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

NOTES
Do NOT take working clothes home. Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties.

NOTES

Do NOT take working clothes home.
Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.

ADDITIONAL INFORMATION

EC Classification

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