ICSC 1684 - 4-NITROBENZOIC ACID

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4-NITROBENZOIC ACID	ICSC: 1684 (April 2008)
para-Nitrobenzoic acid para-Carboxynitrobenzene

CAS #: 62-23-7

EC Number: 200-526-2

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Risk of explosion on contact with potassium hydroxide.	NO open flames.	Use foam, dry powder, carbon dioxide.

PREVENT DISPERSION OF DUST!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough.	Use local exhaust.	Fresh air, rest.
Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness.	Wear safety spectacles.	Rinse with plenty of water (remove contact lenses if easily possible).
Ingestion	Nausea. Vomiting.		Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers.	According to UN GHS Criteria WARNING Causes skin and eye irritation May cause respiratory irritation Transportation UN Classification
STORAGE
Separated from strong oxidants, bases and strong reducing agents.
PACKAGING

4-NITROBENZOIC ACID

ICSC: 1684

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance WHITE-TO-YELLOW CRYSTALS. Physical dangers Dust explosion possible if in powder or granular form, mixed with air. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc. Chemical dangers Reacts with bases, reducing agents and strong oxidants. Decomposes on heating and on burning. This produces toxic fumes including nitrogen oxides.	Formula: C₇H₅NO₄ / HOOCC₆H₄NO₂ Molecular mass: 167.1 Decomposes at 350°C Melting point: 242°C Density: 1.61 g/cm³ Solubility in water, g/100ml at 25°C: 0.03 (poor) Vapour pressure, Pa at 50°C: 1 Flash point: 201°C c.c. Auto-ignition temperature: 300°C Explosive limits, vol% in air: 1.8-? Octanol/water partition coefficient as log Pow: 1.89

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
WHITE-TO-YELLOW CRYSTALS.

Physical dangers
Dust explosion possible if in powder or granular form, mixed with air. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.

Chemical dangers
Reacts with bases, reducing agents and strong oxidants. Decomposes on heating and on burning. This produces toxic fumes including nitrogen oxides.

Formula: C₇H₅NO₄ / HOOCC₆H₄NO₂
Molecular mass: 167.1
Decomposes at 350°C
Melting point: 242°C
Density: 1.61 g/cm³
Solubility in water, g/100ml at 25°C: 0.03 (poor)
Vapour pressure, Pa at 50°C: 1
Flash point: 201°C c.c.
Auto-ignition temperature: 300°C
Explosive limits, vol% in air: 1.8-?
Octanol/water partition coefficient as log Pow: 1.89

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by ingestion. Effects of short-term exposure The substance is irritating to the eyes, respiratory tract and skin.	Inhalation risk A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered. Effects of long-term or repeated exposure Animal tests show that this substance possibly causes toxicity to human reproduction or development.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes, respiratory tract and skin.

Inhalation risk
A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

Effects of long-term or repeated exposure
Animal tests show that this substance possibly causes toxicity to human reproduction or development.

OCCUPATIONAL EXPOSURE LIMITS
MAK: (inhalable fraction): 4 mg/m³; peak limitation category: I(2); carcinogen category: 3; pregnancy risk group: C

ENVIRONMENT

NOTES

ADDITIONAL INFORMATION

EC Classification

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