ICSC 1410 - METHYL CHLOROACETATE

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METHYL CHLOROACETATE	ICSC: 1410 (October 2001)
Chloroacetic acid methyl ester Methyl monochloroacetate Methyl-alpha-chloroacetate

CAS #: 96-34-4

UN #: 2295

EC Number: 202-501-1

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 57°C explosive vapour/air mixtures may be formed.	NO open flames, NO sparks and NO smoking. Above 57°C use a closed system, ventilation and explosion-proof electrical equipment.	Use water spray, dry powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

PREVENT GENERATION OF MISTS!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Shortness of breath. Sore throat.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	MAY BE ABSORBED! Redness. Pain. Skin burns.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .
Eyes	Redness. Pain. Blurred vision.	Wear face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Abdominal pain. Nausea. Vomiting. Diarrhoea.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in covered plastic containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 6.1; UN Subsidiary Risks: 3; UN Pack Group: I
STORAGE
Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers.
PACKAGING
Do not transport with food and feedstuffs.

METHYL CHLOROACETATE

ICSC: 1410

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers The vapour is heavier than air. Chemical dangers Decomposes on burning. This produces corrosive fumes including hydrogen chloride. Reacts with reducing agents and oxidants.	Formula: C₃H₅ClO₂ Molecular mass: 108.53 Boiling point: 129.5°C Melting point: -32.1°C Density: 1.2 g/cm³ Solubility in water, g/100ml at 19.8°C: 5.2 Vapour pressure, Pa at 20°C: 650 Relative vapour density (air = 1): 3.7 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02 Flash point: 57°C o.c. Auto-ignition temperature: 465°C Explosive limits, vol% in air: 7.5-18.5 Octanol/water partition coefficient as log Pow: 0.76 (calculated)

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air.

Chemical dangers
Decomposes on burning. This produces corrosive fumes including hydrogen chloride. Reacts with reducing agents and oxidants.

Formula: C₃H₅ClO₂
Molecular mass: 108.53
Boiling point: 129.5°C
Melting point: -32.1°C
Density: 1.2 g/cm³
Solubility in water, g/100ml at 19.8°C: 5.2
Vapour pressure, Pa at 20°C: 650
Relative vapour density (air = 1): 3.7
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02
Flash point: 57°C o.c.
Auto-ignition temperature: 465°C
Explosive limits, vol% in air: 7.5-18.5
Octanol/water partition coefficient as log Pow: 0.76 (calculated)

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. Effects of short-term exposure The substance is corrosive to the skin. The substance is severely irritating to the eyes. The substance is irritating to the respiratory tract.	Inhalation risk A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

Effects of short-term exposure
The substance is corrosive to the skin. The substance is severely irritating to the eyes. The substance is irritating to the respiratory tract.

Inhalation risk
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS
MAK: 4.5 mg/m³, 1 ppm; peak limitation category: I(1); skin absorption (H); sensitization of skin (SH); pregnancy risk group: C

ENVIRONMENT
The substance is toxic to aquatic organisms.

NOTES

ADDITIONAL INFORMATION

EC Classification
Symbol: T; R: 10-23/25-37/38-41; S: (1/2)-26-37/39-45

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