ICSC 1303 - IMAZALIL

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IMAZALIL	ICSC: 1303 (November 1998)
Allyl 1-(2,4-dichlorophenyl)-2-imidazol-1-ylethyl ether 1-(2-(2,4-Dichlorophenyl)-2-(2-propenyloxy)ethyl)-1H-imidazole Enilconazole

CAS #: 35554-44-0

EC Number: 252-615-0

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Use water spray, powder, foam, carbon dioxide.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation			Fresh air, rest.
Skin		Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Wear safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Nausea.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: chemical protection suit including self-contained breathing apparatus. Sweep spilled substance into covered sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification
STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Keep in a well-ventilated room.
PACKAGING
Do not transport with food and feedstuffs.

IMAZALIL

ICSC: 1303

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance LIGHT YELLOW-TO-BROWN CRYSTALLINE MASS (SOLIDIFIED OIL). Physical dangers Chemical dangers Decomposes on distillation or on burning. This produces toxic fumes of nitrogen oxides and chloride.	Formula: C₁₄H₁₄Cl₂N₂O Molecular mass: 297.2 Boiling point: 319-347°C (estimated) Melting point: 50°C Relative density (water = 1): 1.2 Solubility in water, g/100ml at 20°C: 0.14 Vapour pressure at 20°C: negligible Flash point: 192°C Octanol/water partition coefficient as log Pow: 4.56

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
LIGHT YELLOW-TO-BROWN CRYSTALLINE MASS (SOLIDIFIED OIL).

Physical dangers

Chemical dangers
Decomposes on distillation or on burning. This produces toxic fumes of nitrogen oxides and chloride.

Formula: C₁₄H₁₄Cl₂N₂O
Molecular mass: 297.2
Boiling point: 319-347°C (estimated)
Melting point: 50°C
Relative density (water = 1): 1.2
Solubility in water, g/100ml at 20°C: 0.14
Vapour pressure at 20°C: negligible
Flash point: 192°C
Octanol/water partition coefficient as log Pow: 4.56

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation and by ingestion. Effects of short-term exposure The substance is severely irritating to the eyes.	Inhalation risk Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying. Effects of long-term or repeated exposure The substance may have effects on the liver. This may result in impaired functions and tissue lesions.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Effects of short-term exposure
The substance is severely irritating to the eyes.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.

Effects of long-term or repeated exposure
The substance may have effects on the liver. This may result in impaired functions and tissue lesions.

OCCUPATIONAL EXPOSURE LIMITS
MAK: (inhalable fraction): 2 mg/m³; peak limitation category: I(2); skin absorption (H); pregnancy risk group: C

ENVIRONMENT
The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.

NOTES
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xn, N; R: 20/22-41-50/53; S: (2)-26-39-60-61

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