ICSC 1271 - PROPAQUIZAFOP

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PROPAQUIZAFOP	ICSC: 1271 (June 2011)
2-Isopropylideneamino-oxyethyl (R)-2-(4-(6-chloroquinoxalin-2-yloxy)phenoxy)propionate (R)-2-(((1-Methylethylidene)amino)oxy)ethyl 2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)propanoate

CAS #: 111479-05-1

UN #: 3077

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.		In case of fire in the surroundings, use appropriate extinguishing media.

STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	See Notes.	Use local exhaust or breathing protection.	Fresh air, rest. Seek medical attention if you feel unwell.
Skin	See Notes.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness.	Wear safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	See Notes.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Seek medical attention if you feel unwell.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria WARNING Harmful if inhaled May be harmful if swallowed Very toxic to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 9; UN Pack Group: III
STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Store in an area without drain or sewer access.
PACKAGING
Do not transport with food and feedstuffs.

PROPAQUIZAFOP

ICSC: 1271

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS-TO-BROWN CRYSTALS. Physical dangers Chemical dangers Decomposes on burning. This produces toxic and corrosive fumes including hydrogen chloride and nitrogen oxides.	Formula: C₂₂H₂₂ClN₃O₅ Molecular mass: 443.9 Melting point: 62-64°C Relative density (water = 1): 1.3 Solubility in water, g/100ml at 20°C: 0.06 (very poor) Vapour pressure at 20°C: negligible Octanol/water partition coefficient as log Pow: 4.6

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS-TO-BROWN CRYSTALS.

Physical dangers

Chemical dangers
Decomposes on burning. This produces toxic and corrosive fumes including hydrogen chloride and nitrogen oxides.

Formula: C₂₂H₂₂ClN₃O₅
Molecular mass: 443.9
Melting point: 62-64°C
Relative density (water = 1): 1.3
Solubility in water, g/100ml at 20°C: 0.06 (very poor)
Vapour pressure at 20°C: negligible
Octanol/water partition coefficient as log Pow: 4.6

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its aerosol. Effects of short-term exposure The substance is mildly irritating to the eyes.	Inhalation risk A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered. Effects of long-term or repeated exposure See Notes.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol.

Effects of short-term exposure
The substance is mildly irritating to the eyes.

Inhalation risk
A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered.

Effects of long-term or repeated exposure
See Notes.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

NOTES
Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties.

ADDITIONAL INFORMATION

EC Classification

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