ICSC 1252 - TRIFLUMIZOLE

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TRIFLUMIZOLE	ICSC: 1252 (May 2018)
(E)-4-Chloro-alpha,alpha,alpha-trifluoro-N-(1-imidazol-1-yl-2-propoxyethylidene)-o-toluidine 1-[(1E)-1-[[4-chloro-2-(trifluoromethyl)phenyl]imino]-2-propoxyethyl]-1H-imidazole (1E)-N-[4-chloro-2-(trifluoromethyl)phenyl]-1-(1H-imidazol-1-yl)-2-propoxyethanimine

CAS #: 99387-89-0

UN #: 3077

EC Number: 614-708-8

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.		In case of fire in the surroundings, use appropriate extinguishing media.

STRICT HYGIENE!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation		Use ventilation.	Fresh air, rest.
Skin		Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness.	Wear safety spectacles.	Rinse with plenty of water for several minutes (remove contact lenses if easily possible).
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Harmful if swallowed May cause an allergic skin reaction Suspected of damaging fertility or the unborn child May cause damage to liver through prolonged or repeated exposure Very toxic to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 9; UN Pack Group: III
STORAGE
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Store in an area without drain or sewer access.
PACKAGING
Do not transport with food and feedstuffs.

TRIFLUMIZOLE

ICSC: 1252

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS CRYSTALS. Physical dangers No data. Chemical dangers Decomposes on heating and on burning. This produces toxic and corrosive fumes including nitrogen oxides, hydrogen fluoride, hydrogen chloride and carbon monoxide. Reacts with strong acids and strong bases. This generates toxic, fire and explosion hazard.	Formula: C₁₅H₁₅ClF₃N₃O Molecular mass: 345.8 Melting point: 63°C Boiling point: No boiling point at normal pressure; decomposes at 150°C Density: 1.4 g/cm³ Solubility in water, mg/l at 20°C: 10.2 (practically insoluble) Vapour pressure at 25°C: negligible Octanol/water partition coefficient as log Pow: 4.8 (calculated)

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS CRYSTALS.

Physical dangers
No data.

Chemical dangers
Decomposes on heating and on burning. This produces toxic and corrosive fumes including nitrogen oxides, hydrogen fluoride, hydrogen chloride and carbon monoxide. Reacts with strong acids and strong bases. This generates toxic, fire and explosion hazard.

Formula: C₁₅H₁₅ClF₃N₃O
Molecular mass: 345.8
Melting point: 63°C
Boiling point: No boiling point at normal pressure; decomposes at 150°C
Density: 1.4 g/cm³
Solubility in water, mg/l at 20°C: 10.2 (practically insoluble)
Vapour pressure at 25°C: negligible
Octanol/water partition coefficient as log Pow: 4.8 (calculated)

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of dust and by ingestion. Effects of short-term exposure The substance is mildly irritating to the eyes.	Inhalation risk Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. Effects of long-term or repeated exposure Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the liver. This may result in impaired functions. Animal tests show that this substance possibly causes toxicity to human reproduction or development.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of dust and by ingestion.

Effects of short-term exposure
The substance is mildly irritating to the eyes.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the liver. This may result in impaired functions. Animal tests show that this substance possibly causes toxicity to human reproduction or development.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. Avoid release to the environment in circumstances different to normal use.

NOTES
CAS No. 99387-89-0 of triflumizole is for (E) isomer. CAS No. 68694-11-1 is for unstated stereochemistry. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties.

ADDITIONAL INFORMATION

EC Classification

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