ICSC 1187 - METHYL BENZOATE

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METHYL BENZOATE	ICSC: 1187 (April 2024)
Niobe oil Benzoic acid, methyl ester Benzenecarbonic acid methyl ester Methyl benzenecarboxylate

CAS #: 93-58-3

EC Number: 202-259-7

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Above 83°C explosive vapour/air mixtures may be formed.	NO open flames. Above 83°C use a closed system and ventilation.	Use water spray, foam, dry powder, carbon dioxide.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough.	Use ventilation.	Fresh air, rest.
Skin		Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes		Wear safety spectacles.	Rinse with plenty of water (remove contact lenses if easily possible). Refer for medical attention if irritation persists.
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth. Seek medical attention if you feel unwell.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria WARNING Combustible liquid Harmful to aquatic life Transportation UN Classification
STORAGE
Store only in original container. Well closed. Ventilation along the floor.
PACKAGING

METHYL BENZOATE

ICSC: 1187

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS OILY LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers The vapour is heavier than air. Chemical dangers On combustion, forms toxic gases of carbon monoxide (see ICSC 0023).	Formula: C₈H₈O₂ / C₆H₅COOCH₃ Molecular mass: 136.1 Boiling point: 199°C Melting point: -12°C Relative density (water = 1): 1.09 (20°C) Solubility in water, g/l at 25°C: 2 (slightly soluble) Vapour pressure, Pa at 20°C: 36 Relative vapour density (air = 1): 4.7 Flash point: 83°C c.c. Octanol/water partition coefficient as log Pow: 2.2 Viscosity: 1.33 mm²/s at 20°C Auto-ignition temperature: 542°C Explosive limits, vol% in air: 8.6 - 20

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS OILY LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air.

Chemical dangers
On combustion, forms toxic gases of carbon monoxide (see ICSC 0023).

Formula: C₈H₈O₂ / C₆H₅COOCH₃
Molecular mass: 136.1
Boiling point: 199°C
Melting point: -12°C
Relative density (water = 1): 1.09 (20°C)
Solubility in water, g/l at 25°C: 2 (slightly soluble)
Vapour pressure, Pa at 20°C: 36
Relative vapour density (air = 1): 4.7
Flash point: 83°C c.c.
Octanol/water partition coefficient as log Pow: 2.2
Viscosity: 1.33 mm²/s at 20°C
Auto-ignition temperature: 542°C
Explosive limits, vol% in air: 8.6 - 20

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour. Effects of short-term exposure The substance may cause effects on the central nervous system. This may result in impaired functions.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour.

Effects of short-term exposure
The substance may cause effects on the central nervous system. This may result in impaired functions.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is harmful to aquatic organisms.

NOTES

ADDITIONAL INFORMATION

EC Classification

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