ICSC 1150 - n-BUTYL ETHER

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n-BUTYL ETHER	ICSC: 1150 (April 2017)
1-Butoxybutane Di-n-butyl ether 1,1'-Oxybis(butane)

CAS #: 142-96-1

UN #: 1149

EC Number: 205-575-3

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Flammable. Above 25°C explosive vapour/air mixtures may be formed.	NO open flames, NO sparks and NO smoking. NO contact with hot surfaces. Above 25°C use a closed system, ventilation and explosion-proof electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).	Use foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Dry skin.	Protective gloves.	First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again.
Eyes	Redness. Pain.	Wear safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Burning sensation. Nausea. Sore throat.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Cover the spilled material with foam. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria WARNING Flammable liquid and vapour Causes eye irritation May cause respiratory irritation May be harmful if swallowed and enters airways Harmful to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 3; UN Pack Group: III
STORAGE
Fireproof. Provision to contain effluent from fire extinguishing. Separated from incompatible materials. See Chemical Dangers. Cool. Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access.
PACKAGING
Airtight.

n-BUTYL ETHER

ICSC: 1150

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID. Physical dangers As a result of flow, agitation, etc., electrostatic charges can be generated. Chemical dangers The substance can form explosive peroxides , especially in anhydrous form. Reacts violently with nitrogen trichloride and strong oxidants. Reacts with strong acids.	Formula: C₈H₁₈O / (CH₃CH₂CH₂CH₂)₂O Molecular mass: 130.2 Boiling point: 142°C Melting point: -95°C Density (at 20°C): 0.8 g/cm³ Solubility in water, g/100ml: <0.1 (very poor) Vapour pressure, kPa at 20°C: 0.46 Relative vapour density (air = 1): 4.5 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.0 Viscosity: 0.86 mm²/s at 20°C Flash point: 25°C c.c. Auto-ignition temperature: 175°C Explosive limits, vol% in air: 0.9-8.5 Octanol/water partition coefficient as log Pow: 3.21

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID.

Physical dangers
As a result of flow, agitation, etc., electrostatic charges can be generated.

Chemical dangers
The substance can form explosive peroxides , especially in anhydrous form. Reacts violently with nitrogen trichloride and strong oxidants. Reacts with strong acids.

Formula: C₈H₁₈O / (CH₃CH₂CH₂CH₂)₂O
Molecular mass: 130.2
Boiling point: 142°C
Melting point: -95°C
Density (at 20°C): 0.8 g/cm³
Solubility in water, g/100ml: <0.1 (very poor)
Vapour pressure, kPa at 20°C: 0.46
Relative vapour density (air = 1): 4.5
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.0
Viscosity: 0.86 mm²/s at 20°C
Flash point: 25°C c.c.
Auto-ignition temperature: 175°C
Explosive limits, vol% in air: 0.9-8.5
Octanol/water partition coefficient as log Pow: 3.21

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour. Effects of short-term exposure The substance is mildly irritating to the eyes and respiratory tract. If swallowed the substance may cause vomiting and could result in aspiration pneumonitis.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure The substance defats the skin, which may cause dryness or cracking.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour.

Effects of short-term exposure
The substance is mildly irritating to the eyes and respiratory tract. If swallowed the substance may cause vomiting and could result in aspiration pneumonitis.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure
The substance defats the skin, which may cause dryness or cracking.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is harmful to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. The substance may cause long-term effects in the aquatic environment. Bioaccumulation of this chemical may occur along the food chain, for example in fish.

NOTES
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Check for peroxides prior to distillation; eliminate if found.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xi; R: 10-36/37/38-52/53; S: (2)-61

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