ICSC 1113 - N-PHENYL-1-NAPHTHYLAMINE

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N-PHENYL-1-NAPHTHYLAMINE	ICSC: 1113 (March 1998)
N-(1-Naphthyl)aniline N-Phenyl-alpha-naphthylamine

CAS #: 90-30-2

EC Number: 201-983-0

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

AVOID ALL CONTACT!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Blue lips, fingernails and skin. Confusion. Convulsions. Dizziness. Headache. Nausea. Unconsciousness.	Use local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	MAY BE ABSORBED!	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes		Wear face shield.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	See Inhalation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification
STORAGE
Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
PACKAGING

N-PHENYL-1-NAPHTHYLAMINE

ICSC: 1113

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance WHITE-TO-SLIGHTLY-YELLOWISH CRYSTALS. Physical dangers Chemical dangers Decomposes on burning. This produces toxic fumes including nitrogen oxides.	Formula: C₁₆H₁₃N / C₁₀H₇NHC₆H₅ Molecular mass: 219.30 Melting point: 62-63°C Relative density (water = 1): 1.2 Solubility in water: none Octanol/water partition coefficient as log Pow: 4.2

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
WHITE-TO-SLIGHTLY-YELLOWISH CRYSTALS.

Physical dangers

Chemical dangers
Decomposes on burning. This produces toxic fumes including nitrogen oxides.

Formula: C₁₆H₁₃N / C₁₀H₇NHC₆H₅
Molecular mass: 219.30
Melting point: 62-63°C
Relative density (water = 1): 1.2
Solubility in water: none
Octanol/water partition coefficient as log Pow: 4.2

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion. Effects of short-term exposure The substance may cause effects on the blood. This may result in the formation of methaemoglobin. The effects may be delayed. Medical observation is indicated.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure Repeated or prolonged contact may cause skin sensitization.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

Effects of short-term exposure
The substance may cause effects on the blood. This may result in the formation of methaemoglobin. The effects may be delayed. Medical observation is indicated.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization.

OCCUPATIONAL EXPOSURE LIMITS
MAK: (inhalable fraction): 2 mg/m³; peak limitation category: II(2); pregnancy risk group: C; sensitization of skin (SH)

ENVIRONMENT
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in fish. It is strongly advised not to let the chemical enter into the environment.

NOTES
Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.

ADDITIONAL INFORMATION

EC Classification

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