ICSC 1084 - 1-HEXANOL

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1-HEXANOL	ICSC: 1084 (September 2002)
Hexyl alcohol n-Hexanol n-Hexyl alcohol 1-Hydroxyhexane Amyl carbinol Caproyl alcohol

CAS #: 111-27-3

EC Number: 203-852-3

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Above 63°C explosive vapour/air mixtures may be formed.	NO open flames. Above 63°C use a closed system and ventilation.	Use alcohol-resistant foam, dry powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest.
Skin	Dry skin.	Protective gloves.	Rinse and then wash skin with water and soap.
Eyes	Redness. Pain.	Wear safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Burning sensation.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification
STORAGE
Separated from strong oxidants.
PACKAGING

1-HEXANOL

ICSC: 1084

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers Chemical dangers Reacts with strong oxidants.	Formula: C₆H₁₄O / CH₃(CH₂)₄CH₂OH Molecular mass: 102.2 Boiling point: 157°C Melting point: -44.6°C Relative density (water = 1): 0.82 Solubility in water, g/100ml at 20°C: 0.59 Vapour pressure, kPa at 25°C: 0.124 Relative vapour density (air = 1): 3.52 Relative density of the vapour/air-mixture at 20°C (air = 1): 1 Flash point: 63°C c.c. Auto-ignition temperature: 290°C Explosive limits, vol% in air: 1.2-7.7 (calculated) Octanol/water partition coefficient as log Pow: 2.03

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers

Chemical dangers
Reacts with strong oxidants.

Formula: C₆H₁₄O / CH₃(CH₂)₄CH₂OH
Molecular mass: 102.2
Boiling point: 157°C
Melting point: -44.6°C
Relative density (water = 1): 0.82
Solubility in water, g/100ml at 20°C: 0.59
Vapour pressure, kPa at 25°C: 0.124
Relative vapour density (air = 1): 3.52
Relative density of the vapour/air-mixture at 20°C (air = 1): 1
Flash point: 63°C c.c.
Auto-ignition temperature: 290°C
Explosive limits, vol% in air: 1.2-7.7 (calculated)
Octanol/water partition coefficient as log Pow: 2.03

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation and by ingestion. Effects of short-term exposure The substance is irritating to the respiratory tract and skin. The substance is severely irritating to the eyes. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure The substance defats the skin, which may cause dryness or cracking.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Effects of short-term exposure
The substance is irritating to the respiratory tract and skin. The substance is severely irritating to the eyes. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure
The substance defats the skin, which may cause dryness or cracking.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT

NOTES

ADDITIONAL INFORMATION

EC Classification
Symbol: Xn; R: 22; S: (2)-24/25

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