ICSC 0676 - 1,2,4,5-TETRACHLOROBENZENE

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1,2,4,5-TETRACHLOROBENZENE	ICSC: 0676 (November 2003)
Benzene tetrachloride s-Tetrachlorobenzene

CAS #: 95-94-3

EC Number: 202-466-2

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with oxidizing agents.	NO open flames.	Use powder, carbon dioxide.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough.	Use local exhaust.	Fresh air, rest. Refer for medical attention.
Skin		Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes		Wear safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: P2 filter respirator for harmful particles. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.	According to UN GHS Criteria Transportation UN Classification
STORAGE
Separated from strong oxidants.
PACKAGING

1,2,4,5-TETRACHLOROBENZENE

ICSC: 0676

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS CRYSTALS. Physical dangers Chemical dangers Decomposes on burning. This produces toxic and corrosive fumes including hydrogen chloride. Reacts with strong oxidants.	Formula: C₆H₂Cl₄ Molecular mass: 215.9 Boiling point: 243-246°C Melting point: 139-140°C Density: 1.83 g/cm³ Solubility in water, mg/l at 25°C: 2.16 Vapour pressure, Pa at 25°C: 0.7 Relative vapour density (air = 1): 7.4 Flash point: 155°C c.c. Octanol/water partition coefficient as log Pow: 4.9

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS CRYSTALS.

Physical dangers

Chemical dangers
Decomposes on burning. This produces toxic and corrosive fumes including hydrogen chloride. Reacts with strong oxidants.

Formula: C₆H₂Cl₄
Molecular mass: 215.9
Boiling point: 243-246°C
Melting point: 139-140°C
Density: 1.83 g/cm³
Solubility in water, mg/l at 25°C: 2.16
Vapour pressure, Pa at 25°C: 0.7
Relative vapour density (air = 1): 7.4
Flash point: 155°C c.c.
Octanol/water partition coefficient as log Pow: 4.9

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. Effects of short-term exposure	Inhalation risk Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. Effects of long-term or repeated exposure The substance may have effects on the liver. This may result in liver impairment.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Effects of short-term exposure

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

Effects of long-term or repeated exposure
The substance may have effects on the liver. This may result in liver impairment.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in fish.

NOTES
Health effects of exposure to the substance have not been investigated adequately.

ADDITIONAL INFORMATION

EC Classification

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