ICSC 0450 - 2-DIMETHYLAMINOETHYL METHACRYLATE

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2-DIMETHYLAMINOETHYL METHACRYLATE	ICSC: 0450 (April 2006)
Dimethylamino-ethylmethacrylate N,N-Dimethylaminoethyl methacrylate Methacrylic acid, 2-(dimethylamino)ethyl ester

CAS #: 2867-47-2

UN #: 2522

EC Number: 220-688-8

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 68°C explosive vapour/air mixtures may be formed.	NO open flames. Above 68°C use a closed system and ventilation.	Use water spray, powder, alcohol-resistant foam, carbon dioxide.

PREVENT GENERATION OF MISTS!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest.
Skin	Skin burns. Pain.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
Eyes	Redness. Pain. Severe deep burns.	Wear face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Abdominal pain. Diarrhoea. Nausea. Vomiting. Burning sensation. Shock or collapse.	Do not eat, drink, or smoke during work.	Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Combustible liquid Causes severe skin burns and eye damage Harmful to aquatic life Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: II
STORAGE
Separated from metals, oxidants, strong reducing agents and food and feedstuffs. Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access.
PACKAGING
Do not transport with food and feedstuffs.

2-DIMETHYLAMINOETHYL METHACRYLATE

ICSC: 0450

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS-TO-LIGHT-YELLOW LIQUID. Physical dangers Chemical dangers The substance may polymerize under the influence of heat, light, oxidants, reducing agents and metals. This generates fire or explosion hazard. Decomposes on burning. This produces toxic fumes including nitrogen oxides. Attacks some forms of rubber.	Formula: C₈H₁₅NO₂ Molecular mass: 157.2 Boiling point: 186°C Melting point: -30°C Relative density (water = 1): 0.93 Solubility in water, g/100ml at 25°C: 10.6 Vapour pressure, kPa at 25°C: 0.11 Relative vapour density (air = 1): 5.4 Flash point: 68°C c.c. Auto-ignition temperature: 255°C Explosive limits, vol% in air: 1.2-? Octanol/water partition coefficient as log Pow: 1.13

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS-TO-LIGHT-YELLOW LIQUID.

Physical dangers

Chemical dangers
The substance may polymerize under the influence of heat, light, oxidants, reducing agents and metals. This generates fire or explosion hazard. Decomposes on burning. This produces toxic fumes including nitrogen oxides. Attacks some forms of rubber.

Formula: C₈H₁₅NO₂
Molecular mass: 157.2
Boiling point: 186°C
Melting point: -30°C
Relative density (water = 1): 0.93
Solubility in water, g/100ml at 25°C: 10.6
Vapour pressure, kPa at 25°C: 0.11
Relative vapour density (air = 1): 5.4
Flash point: 68°C c.c.
Auto-ignition temperature: 255°C
Explosive limits, vol% in air: 1.2-?
Octanol/water partition coefficient as log Pow: 1.13

EXPOSURE & HEALTH EFFECTS
Routes of exposure Effects of short-term exposure The substance is corrosive to the eyes and skin. The substance is irritating to the respiratory tract. Corrosive on ingestion.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure

Effects of short-term exposure
The substance is corrosive to the eyes and skin. The substance is irritating to the respiratory tract. Corrosive on ingestion.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS
MAK sensitization of skin (SH)

ENVIRONMENT
The substance is harmful to aquatic organisms.

NOTES
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xn; R: 21/22-36/38-43; S: (2)-26-28

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