ICSC 0443 - CLOPYRALID

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CLOPYRALID	ICSC: 0443 (November 1997)
3,6-Dichloropyridine-2-carboxylic acid 3,6-Dichloropicolinic acid 3,6-DCP

CAS #: 1702-17-6

EC Number: 216-935-4

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible.	NO open flames.	Use water spray, powder.

PREVENT DISPERSION OF DUST!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat.	Use local exhaust or breathing protection.	Fresh air, rest.
Skin	Redness.	Protective gloves.
Eyes	Redness. Pain.	Wear safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification
STORAGE
Do NOT store or transport in containers made from aluminium.
PACKAGING

CLOPYRALID

ICSC: 0443

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance ODOURLESS WHITE OR COLOURLESS CRYSTALS. Physical dangers Chemical dangers Decomposes on burning. This produces toxic and corrosive fumes of nitrogen oxides and chlorine (see ICSC 0126). The solution is corrosive to aluminum, iron and tin.	Formula: C₆H₃Cl₂NO₂ / (C₅H₂N)Cl₂COOH Molecular mass: 192.0 Melting point: 151-152°C Solubility in water at 20°C: poor Vapour pressure, Pa at 25°C: 0.002

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
ODOURLESS WHITE OR COLOURLESS CRYSTALS.

Physical dangers

Chemical dangers
Decomposes on burning. This produces toxic and corrosive fumes of nitrogen oxides and chlorine (see ICSC 0126). The solution is corrosive to aluminum, iron and tin.

Formula: C₆H₃Cl₂NO₂ / (C₅H₂N)Cl₂COOH
Molecular mass: 192.0
Melting point: 151-152°C
Solubility in water at 20°C: poor
Vapour pressure, Pa at 25°C: 0.002

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body through the skin and by ingestion. Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract.	Inhalation risk Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body through the skin and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract.

Inhalation risk
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
Avoid release to the environment in circumstances different to normal use.

NOTES
Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xi, N; R: 41-51/53; S: (2)-26-39-61

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