ICSC 0417 - BIS(2-CHLOROETHYL) ETHER

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BIS(2-CHLOROETHYL) ETHER	ICSC: 0417 (April 2000)
Dichloroethyl ether 2,2'-Dichloroethyl ether 1,1'-Oxybis(2-chloro)ethane sym-Dichloroethyl ether Diethylene glycol dichloride

CAS #: 111-44-4

UN #: 1916

EC Number: 203-870-1

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 55°C explosive vapour/air mixtures may be formed.	NO open flames, NO sparks and NO smoking. Above 55°C use a closed system and ventilation.	Use water spray, foam, powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water. NO direct contact with water.

PREVENT GENERATION OF MISTS!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Sore throat. Nausea. Vomiting. Burning sensation. Laboured breathing. Symptoms may be delayed. See Notes.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Half-upright position. Refer for medical attention.
Skin	MAY BE ABSORBED!	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .
Eyes	Redness. Pain.	Wear face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Abdominal pain. Nausea. Vomiting. Burning sensation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: chemical protection suit. Ventilation. Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 6.1; UN Subsidiary Risks: 3; UN Pack Group: II
STORAGE
Fireproof. Separated from food and feedstuffs. See Chemical Dangers. Keep in the dark. Well closed.
PACKAGING
Do not transport with food and feedstuffs. Marine pollutant.

BIS(2-CHLOROETHYL) ETHER

ICSC: 0417

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance CLEAR COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers The vapour is heavier than air. Chemical dangers The substance can form explosive peroxides on exposure to air and light. Decomposes on burning. Decomposes on contact with water. This produces toxic fumes including hydrogen chloride. Reacts with strong oxidants. Reacts violently with chlorosulfonic acid and oleum.	Formula: C₄H₈Cl₂O / (ClCH₂CH₂)₂O Molecular mass: 143.02 Boiling point: 178°C Melting point: -50°C Relative density (water = 1): 1.22 Vapour pressure, kPa at 25°C: 0.206 Relative vapour density (air = 1): 4.9 Flash point: 55°C c.c. Auto-ignition temperature: 369°C Explosive limits, vol% in air: 2.7-? Octanol/water partition coefficient as log Pow: 1.29

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
CLEAR COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air.

Chemical dangers
The substance can form explosive peroxides on exposure to air and light. Decomposes on burning. Decomposes on contact with water. This produces toxic fumes including hydrogen chloride. Reacts with strong oxidants. Reacts violently with chlorosulfonic acid and oleum.

Formula: C₄H₈Cl₂O / (ClCH₂CH₂)₂O
Molecular mass: 143.02
Boiling point: 178°C
Melting point: -50°C
Relative density (water = 1): 1.22
Vapour pressure, kPa at 25°C: 0.206
Relative vapour density (air = 1): 4.9
Flash point: 55°C c.c.
Auto-ignition temperature: 369°C
Explosive limits, vol% in air: 2.7-?
Octanol/water partition coefficient as log Pow: 1.29

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. Effects of short-term exposure The substance is irritating to the eyes and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes. Exposure far above the OEL could cause death. The effects may be delayed. Medical observation is indicated.	Inhalation risk A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure Repeated or prolonged contact with skin may cause dermatitis.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes. Exposure far above the OEL could cause death. The effects may be delayed. Medical observation is indicated.

Inhalation risk
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 5 ppm as TWA; 10 ppm as STEL; (skin); A4 (not classifiable as a human carcinogen). MAK: 59 mg/m³, 10 ppm; peak limitation category: I(1); skin absorption (H)

ENVIRONMENT

NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered. An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Check for peroxides prior to distillation; eliminate if found.

NOTES

The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Check for peroxides prior to distillation; eliminate if found.

ADDITIONAL INFORMATION

EC Classification
Symbol: T+; R: 10-26/27/28-40; S: (1/2)-7/9-27-28-36/37-45

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