ICSC 0149 - DINOSEB

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DINOSEB	ICSC: 0149 (June 2011)
2,4-Dinitro-6-sec-butylphenol 2-sec-Butyl-4,6-dinitrophenol 2-(1-Methylpropyl)-4,6-dinitrophenol 2,4-Dinitro-6-(1-methylpropyl)phenol

CAS #: 88-85-7

UN #: 2779

EC Number: 201-861-7

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on confinement and exposure to high temperatures.	NO open flames.	Use water spray, foam, powder, carbon dioxide. Combat fire from a sheltered position.

AVOID ALL CONTACT! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Sweating. Headache. Laboured breathing. Nausea. Vomiting. Fever. Convulsions. Unconsciousness. Cyanosis	Use ventilation (not if powder), local exhaust or breathing protection.	Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Skin	EASILY ABSORBED! Redness. Further see Inhalation.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer immediately for medical attention.
Eyes	Redness. Pain.	Wear face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Abdominal pain. Further see Inhalation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Rest. Give a slurry of activated charcoal in water to drink. Refer immediately for medical attention.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Fatal if swallowed, in contact with skin or if inhaled Causes serious eye irritation May damage fertility or the unborn child Very toxic to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: II
STORAGE
Provision to contain effluent from fire extinguishing. Separated from bases and food and feedstuffs. Cool. Keep in a well-ventilated room. Well closed. Store in an area without drain or sewer access.
PACKAGING
Do not transport with food and feedstuffs. Marine pollutant.

DINOSEB

ICSC: 0149

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance ORANGE CRYSTALS WITH PUNGENT ODOUR. Physical dangers Chemical dangers Decomposes on heating. This produces toxic fumes including nitrogen oxides. The solution in water is a weak acid. Attacks many metals in the presence of water.	Formula: C₁₀H₁₂N₂O₅ Molecular mass: 240.2 Melting point: 38-42°C Boiling point: 332°C Relative density (water = 1): 1.3 (30°C) Solubility in water, g/100ml at 20°C: 0.005 (very poor) Vapour pressure, Pa at 20°C: 0.007 Relative vapour density (air = 1): 8.3 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00 Flash point: >100°C Octanol/water partition coefficient as log Pow: 3.69

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
ORANGE CRYSTALS WITH PUNGENT ODOUR.

Physical dangers

Chemical dangers
Decomposes on heating. This produces toxic fumes including nitrogen oxides. The solution in water is a weak acid. Attacks many metals in the presence of water.

Formula: C₁₀H₁₂N₂O₅
Molecular mass: 240.2
Melting point: 38-42°C
Boiling point: 332°C
Relative density (water = 1): 1.3 (30°C)
Solubility in water, g/100ml at 20°C: 0.005 (very poor)
Vapour pressure, Pa at 20°C: 0.007
Relative vapour density (air = 1): 8.3
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: >100°C
Octanol/water partition coefficient as log Pow: 3.69

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation, through the skin and by ingestion. Effects of short-term exposure The substance is irritating to the eyes. The substance may cause effects on the central nervous system. Exposure at high levels could cause death.	Inhalation risk A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster. Effects of long-term or repeated exposure The substance may have effects on the hematopoetic system. May cause reproductive toxicity in humans.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes. The substance may cause effects on the central nervous system. Exposure at high levels could cause death.

Inhalation risk
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.

Effects of long-term or repeated exposure
The substance may have effects on the hematopoetic system. May cause reproductive toxicity in humans.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to bees, birds and mammals. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.

NOTES
Temperature of decomposition is unknown in the literature. Depending on the degree of exposure, periodic medical examination is suggested. Carrier solvents used in commercial formulations may change physical and toxicological properties. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Do NOT take working clothes home.

ADDITIONAL INFORMATION

EC Classification
Symbol: T, N; R: 61-62-24/25-36-44-50/53; S: 53-45-60-61; Note: E

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