ICSC 0114 - tert-BUTANOL

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tert-BUTANOL	ICSC: 0114 (April 2008)
tert-Butyl alcohol 2-Methyl-2-propanol 1,1-Dimethylethanol Trimethyl carbinol 2-Methylpropan-2-ol

CAS #: 75-65-0

UN #: 1120

EC Number: 200-889-7

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Highly flammable. Vapour/air mixtures are explosive. Heating will cause rise in pressure with risk of bursting.	NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.	Use water spray, alcohol-resistant foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Dizziness. Drowsiness. Nausea. Headache. Vomiting.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Redness.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Wear safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	See Inhalation.	Do not eat, drink, or smoke during work.	Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Wash away remainder with plenty of water.	According to UN GHS Criteria DANGER Highly flammable liquid and vapour May be harmful if swallowed May cause drowsiness and dizziness Causes eye irritation Transportation UN Classification UN Hazard Class: 3; UN Pack Group: II
STORAGE
Fireproof. Separated from strong oxidants and strong acids.
PACKAGING

tert-BUTANOL

ICSC: 0114

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID OR CRYSTALLINE POWDER WITH CHARACTERISTIC ODOUR. Physical dangers The vapour mixes well with air, explosive mixtures are easily formed. Chemical dangers Decomposes on contact with strong mineral acids or strong oxidants. This generates fire and explosion hazard.	Formula: C₄H₁₀O / (CH₃)₃COH Molecular mass: 74.1 Boiling point: 83°C Melting point: 25°C Relative density (water = 1): 0.8 Solubility in water: miscible Vapour pressure, kPa at 20°C: 4.1 Relative vapour density (air = 1): 2.6 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06 Flash point: 11°C c.c. Auto-ignition temperature: 470°C Explosive limits, vol% in air: 1.7-8.0 Octanol/water partition coefficient as log Pow: 0.3

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID OR CRYSTALLINE POWDER WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour mixes well with air, explosive mixtures are easily formed.

Chemical dangers
Decomposes on contact with strong mineral acids or strong oxidants. This generates fire and explosion hazard.

Formula: C₄H₁₀O / (CH₃)₃COH
Molecular mass: 74.1
Boiling point: 83°C
Melting point: 25°C
Relative density (water = 1): 0.8
Solubility in water: miscible
Vapour pressure, kPa at 20°C: 4.1
Relative vapour density (air = 1): 2.6
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06
Flash point: 11°C c.c.
Auto-ignition temperature: 470°C
Explosive limits, vol% in air: 1.7-8.0
Octanol/water partition coefficient as log Pow: 0.3

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour and by ingestion. Effects of short-term exposure The substance is irritating to the eyes. The substance may cause effects on the central nervous system. Exposure far above the OEL could cause lowering of consciousness.	Inhalation risk A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure Repeated or prolonged contact with skin may cause dermatitis.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes. The substance may cause effects on the central nervous system. Exposure far above the OEL could cause lowering of consciousness.

Inhalation risk
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 100 ppm as TWA; A4 (not classifiable as a human carcinogen). MAK: 62 mg/m³, 20 ppm; peak limitation category: II(4); pregnancy risk group: C

ENVIRONMENT

NOTES
The odour warning when the exposure limit value is exceeded is insufficient.

ADDITIONAL INFORMATION

EC Classification
Symbol: F, Xn; R: 11-20-36/37; S: (2)-9-16-46

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