ICSC 0076 - TETRACHLOROETHYLENE

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TETRACHLOROETHYLENE	ICSC: 0076 (April 2013)
PER PCE Ethylene Tetrachloride PERC Tetracap 1,1,2,2-tetrachloroethene 1,1,2,2-Tetrachloroethylene Perchloroethylene Tetrachloroethene

CAS #: 127-18-4

UN #: 1897

EC Number: 204-825-9

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with metals. See Chemical Dangers.	NO open flames, NO sparks and NO smoking. NO contact with hot surfaces or finely divided metals. NO contact with metals. See Chemical Dangers	In case of fire in the surroundings, use appropriate extinguishing media.

STRICT HYGIENE! PREVENT GENERATION OF MISTS!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Dizziness. Headache. Drowsiness. Nausea. Unconsciousness.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Artificial respiration may be needed. Refer immediately for medical attention.
Skin	Dry skin. Redness. Burning sensation.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness. Burning sensation. Pain.	Wear safety goggles or face shield.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Sore throat. Aspiration hazard! See Inhalation. Cardiac dysrhythmia. Respiratory arrest.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance and complete protective clothing. Ventilation. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria WARNING Causes skin irritation Suspected of causing cancer May be harmful if swallowed and enters airways May cause drowsiness or dizziness Toxic to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: III
STORAGE
Separated from metals, ignition sources and food and feedstuffs. See Chemical Dangers. Keep in the dark. Keep in a well-ventilated room. Dry. Cool.
PACKAGING
Do not transport with food and feedstuffs. Marine pollutant.

TETRACHLOROETHYLENE

ICSC: 0076

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers The vapour is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen. Chemical dangers Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes of hydrogen chloride, phosgene and chlorine. Decomposes slowly on contact with moisture. This produces trichloroacetic acid and hydrochloric acid. Reacts violently with finely divided metals. This generates fire and explosion hazard.	Formula: C₂Cl₄ / Cl₂C=CCl₂ Molecular mass: 165.8 Boiling point: 121°C Melting point: -22°C Density (at 20°C): 1.62 g/cm³ Solubility in water, g/100ml at 20°C: 0.015 Vapour pressure, kPa at 20°C: 1.9 Relative vapour density (air = 1): 5.7 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.09 Octanol/water partition coefficient as log Pow: 3.4 Auto-ignition temperature: > 650°C

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen.

Chemical dangers
Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes of hydrogen chloride, phosgene and chlorine. Decomposes slowly on contact with moisture. This produces trichloroacetic acid and hydrochloric acid. Reacts violently with finely divided metals. This generates fire and explosion hazard.

Formula: C₂Cl₄ / Cl₂C=CCl₂
Molecular mass: 165.8
Boiling point: 121°C
Melting point: -22°C
Density (at 20°C): 1.62 g/cm³
Solubility in water, g/100ml at 20°C: 0.015
Vapour pressure, kPa at 20°C: 1.9
Relative vapour density (air = 1): 5.7
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.09
Octanol/water partition coefficient as log Pow: 3.4
Auto-ignition temperature: > 650°C

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation, by ingestion and through the skin. Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract. If swallowed the substance may cause vomiting and could result in aspiration pneumonitis. The substance may cause effects on the central nervous system. Exposure at high levels could cause unconsciousness.	Inhalation risk A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the liver, kidneys and central nervous system. This substance is probably carcinogenic to humans.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation, by ingestion and through the skin.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. If swallowed the substance may cause vomiting and could result in aspiration pneumonitis. The substance may cause effects on the central nervous system. Exposure at high levels could cause unconsciousness.

Inhalation risk
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the liver, kidneys and central nervous system. This substance is probably carcinogenic to humans.

OCCUPATIONAL EXPOSURE LIMITS
TLV: 25 ppm as TWA; 100 ppm as STEL; A3 (confirmed animal carcinogen with unknown relevance to humans); BEI issued. MAK: 69 mg/m³, 10 ppm; peak limitation category: II(2); skin absorption (H); carcinogen category: 3; pregnancy risk group: C. EU-OEL: 138 mg/m³, 20 ppm as TWA; 275 mg/m³, 40 ppm as STEL; (skin)

ENVIRONMENT
The substance is toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment.

NOTES
Depending on the degree of exposure, periodic medical examination is suggested. The odour warning when the exposure limit value is exceeded is insufficient. Do NOT use in the vicinity of a fire or a hot surface, or during welding. Use of alcoholic beverages enhances the harmful effect.

ADDITIONAL INFORMATION

EC Classification
Symbol: Xn, N; R: 40-51/53; S: (2)-23-36/37-61

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