ICSC 0002 - 1,2-DIBROMO-3-CHLOROPROPANE

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1,2-DIBROMO-3-CHLOROPROPANE	ICSC: 0002 (April 2017)
3-Chloro-1,2-dibromopropane DBCP 1-Chloro-2,3-dibromopropane

CAS #: 96-12-8

UN #: 2872

EC Number: 202-479-3

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 77°C explosive vapour/air mixtures may be formed.	NO open flames. Above 77°C use a closed system and ventilation.	Use water spray, powder, foam, carbon dioxide.

AVOID ALL CONTACT! PREVENT GENERATION OF MISTS! IN ALL CASES CONSULT A DOCTOR!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Burning sensation. Cough. Sore throat. Headache. Shortness of breath. Drowsiness. Nausea.	Use local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Redness.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .
Eyes	Redness. Pain.	Wear safety goggles or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Burning sensation. Sore throat. Nausea. Vomiting. Drowsiness.	Do not eat, drink, or smoke during work.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Combustible liquid Fatal if inhaled Toxic if swallowed Harmful in contact with skin Causes skin and eye irritation May cause genetic defects May cause cancer May damage fertility or the unborn child May cause damage to organs through prolonged or repeated exposure May cause respiratory irritation May cause drowsiness or dizziness Harmful to aquatic life with long lasting effects Transportation UN Classification UN Hazard Class: 6.1; UN Pack Group: II
STORAGE
Separated from food and feedstuffs and metals such as aluminium or magnesium. Well closed. Store in an area without drain or sewer access. Ventilation along the floor.
PACKAGING
Unbreakable packaging. Put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.

1,2-DIBROMO-3-CHLOROPROPANE

ICSC: 0002

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH PUNGENT ODOUR. TECHNICAL-GRADE PRODUCT: AMBER-TO-DARK BROWN LIQUID. Physical dangers The vapour is heavier than air. Chemical dangers Decomposes on heating above the boiling point. This produces toxic and corrosive fumes including hydrogen bromide and hydrogen chloride. Reacts in the presence of water with aluminium, magnesium, tin and their alloys. Attacks some forms of rubber and coatings.	Formula: C₃H₅Br₂Cl Molecular mass: 236.4 Boiling point: 196°C Melting point: 6°C Relative density (water = 1): 2.1 Solubility in water, g/l at 20°C: 1.2 (poor) Vapour pressure, Pa at 20°C: 77 Relative vapour density (air = 1): 8.16 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01 Flash point: 77°C o.c. Octanol/water partition coefficient as log Pow: 2.96

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH PUNGENT ODOUR. TECHNICAL-GRADE PRODUCT: AMBER-TO-DARK BROWN LIQUID.

Physical dangers
The vapour is heavier than air.

Chemical dangers
Decomposes on heating above the boiling point. This produces toxic and corrosive fumes including hydrogen bromide and hydrogen chloride. Reacts in the presence of water with aluminium, magnesium, tin and their alloys. Attacks some forms of rubber and coatings.

Formula: C₃H₅Br₂Cl
Molecular mass: 236.4
Boiling point: 196°C
Melting point: 6°C
Relative density (water = 1): 2.1
Solubility in water, g/l at 20°C: 1.2 (poor)
Vapour pressure, Pa at 20°C: 77
Relative vapour density (air = 1): 8.16
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
Flash point: 77°C o.c.
Octanol/water partition coefficient as log Pow: 2.96

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the central nervous system and kidneys. This may result in impaired functions. Exposure could cause lowering of consciousness.	Inhalation risk A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure The substance may have effects on the liver, lungs, kidneys and testes. This may result in impaired functions and tissue lesions. May cause heritable genetic damage to human germ cells. This substance is probably carcinogenic to humans. Causes toxicity to human reproduction or development.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the central nervous system and kidneys. This may result in impaired functions. Exposure could cause lowering of consciousness.

Inhalation risk
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
The substance may have effects on the liver, lungs, kidneys and testes. This may result in impaired functions and tissue lesions. May cause heritable genetic damage to human germ cells. This substance is probably carcinogenic to humans. Causes toxicity to human reproduction or development.

OCCUPATIONAL EXPOSURE LIMITS
MAK: skin absorption (H); carcinogen category: 2. MAK: germ cell mutagen group: 2

ENVIRONMENT
The substance is harmful to aquatic organisms. The substance may cause long-term effects in the aquatic environment.

NOTES
Depending on the degree of exposure, periodic medical examination is suggested. An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home.

ADDITIONAL INFORMATION

EC Classification
Symbol: T; R: 45-46-60-25-48/20/22-52/53; S: 53-45-61; Note: E

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